A critical zone observatory dedicated to suspended sediment transport: The meso-scale Galabre catchment (southern French Alps)

The 20 km² Galabre catchment belongs to the French network of critical zone observatories (OZCAR; Gaillardet et al., Vadose Zone Journal, 2018, 17(1), 1–24). It is representative of the sedimentary lithology and meteorological forcing found in Mediterranean and mountainous areas. Due to the presence of highly erodible and sloping badlands on various lithologies, the site was instrumented in 2007 to understand the dynamics of suspended sediments (SS) in such areas. Two meteorological stations including measurements of air temperature, wind speed and direction, air moisture, rainfall intensity, raindrop size and velocity distribution were installed both in the upper and lower part of the catchment. At the catchment outlet, a gauging station records the water level, temperature and turbidity (10 min time-step). Stream water samples are collected automatically to estimate SS concentration-turbidity relationships, allowing quantification of SS fluxes with known uncertainty. The sediment samples are further characterized by measuring their particle size distributions and by applying a low-cost sediment fingerprinting approach using spectrocolorimetric tracers. Thus, the contributions of badlands located on different lithologies to total SS flux are quantified at a high temporal resolution, providing the opportunity to better analyse the links between meteorological forcing variability and watershed hydrosedimentary response. The set of measurements was extended to the dissolved phase in 2017. Both stream water electrical conductivity and major ion concentrations are measured each week and every 3 h during storm events. This extension of measurements to the dissolved phase will allow progress in understanding both the origin of the water during the events and the partitioning between particulate and dissolved fluxes of solutes in the critical zone. All data sets are available at https://doi.osug.fr/public/DRAIXBLEONE_GAL/index.html .     

Describing alpine lake influence on stream network temperatures: A statistical modelling approach

Systematic variations in atmospheric heat exchange, surface residence time, and groundwater influx across montane stream networks commonly produce an increasing stream temperature trend with decreasing elevation. However, complex stream temperature profiles that differ from this common longitudinal trend also exist, suggesting that stream temperatures may be influenced by complex interactions among hydrologic and atmospheric processes. Lakes within stream networks form one potential source of temperature profile complexity due to the spatially variable contribution of lake-sourced water to stream flow. We investigated temperature profile complexity in a multi-season stream temperature dataset collected across a montane stream network containing many alpine lakes. This investigation was performed by making comparisons between multiple statistical models that used different combinations of stream and lake characteristics to represent specific hypotheses for the controls on stream temperature. The compared models included a set of models which used a topographically derived estimate of the hydrologic influence of lakes to separate and quantify the effects of stream elevation and lake source-water contributions to longitudinal stream temperature patterns. This source-water mixing model provided a parsimonious explanation for complex stream-network temperature patterns in the summer and autumn, and this approach may be further applicable to other systems where stream temperatures are influenced by multiple water sources. Simpler models that discounted lake effects were more optimal during the winter and spring, suggesting that complex patterns in stream temperature profiles may emerge and subside temporally, across seasons, in response to diversity of water temperatures from different sources.     

Sources of variability in springwater chemistry in Fool Creek,a high-elevation catchment of the Rocky Mountains,Colorado, USA

Springs are the point of origin for most headwater streams and are important regulators of their chemical composition. We analysed solute concentrations of water emerging from 57 springs within the 3 km² Fool Creek catchment at the Fraser Experimental Forest and considered sources of spatial variation among them and their influence on the chemical composition of downstream water. On average, calcium and acid neutralizing capacity (bicarbonate-ANC) comprised 50 and 90% of the cation and anion charge respectively, in both spring and stream water. Variation in inorganic chemical composition among springs reflected distinct groundwater sources and catchment geology. Springs emerging through glacial deposits in the upper portion of the catchment were the most dilute and similar to snowmelt, whereas lower elevation springs were more concentrated in cations and ANC. Water emerging from a handful of springs in a geologically faulted portion of the catchment were more concentrated than all others and had a predominant effect on downstream ion concentrations. Chemical similarity indicated that these springs were linked along surface and subsurface flowpaths. This survey shows that springwater chemistry is influenced at nested spatial scales including broad geologic conditions, elevational and spatial attributes and isolated local features. Our results highlight the role of overlapping factors on solute export from headwater catchments.     

The Fernow Experimental Forest,West Virginia,USA: Insights,datasets, and opportunities

Long-term experimental watershed studies have significantly influenced our global understanding of hydrological processes. The discovery and characterization of how stream water quantity and quality respond to a changing environment (e.g. land-use change, acidic deposition) has only been possible due to the establishment of catchments devoted to long-term study. One such catchment is the Fernow Experimental Forest (FEF) located in the headwaters of the Appalachian Mountains in West Virginia, a region that provides essential freshwater ecosystem services to eastern and mid-western United States communities. Established in 1934, the FEF is among the earliest experimental watershed studies in the Eastern United States that continues to address emergent challenges to forest ecosystems, including climate change and other threats to forest health. This data note describes available data and presents some findings from more than 50 years of hydrologic research at the FEF. During the first few decades, research at the FEF focused on the relationship between forest management and hydrological processes—especially those related to the overall water balance. Later, research included the examination of interactions between hydrology and soil erosion, biogeochemistry, N-saturation, and acid deposition. Hydro-climatologic and water quality datasets from long-term measurements and data from short-duration studies are publicly available to provide new insights and foster collaborations that will continue to advance our understanding of hydrology in forested headwater catchments. As a result of its rich history of research and abundance of long-term data, the FEF is positioned to continue to advance understanding of forest ecosystems in a time of unprecedented change.     

Forest operations,tree species composition and decline in rainfall explain runoff changes in the Nacimiento experimental catchments,south central Chile

Few long-term studies have explored how intensively managed short rotation forest plantations interact with climate variability. We examine how prolonged severe drought and forest operations affect runoff in 11 experimental catchments on private corporate forest land near Nacimiento in south central Chile over the period 2008–2019. The catchments (7.7–414 ha) contain forest plantations of exotic fast-growing species (Pinus radiata, Eucalyptus spp.) at various stages of growth in a Mediterranean climate (mean long-term annual rainfall = 1381 mm). Since 2010, a drought, unprecedented in recent history, has reduced rainfall at Nacimiento by 20%, relative to the long-term mean. Pre-drought runoff ratios were <0.2 under 8-year-old Eucalyptus; >0.4 under 21-year-old Radiata pine and >0.8 where herbicide treatments had controlled vegetation for 2 years in 38% of the catchment area. Early in the study period, clearcutting of Radiata pine (85%–95% of catchment area) increased streamflow by 150 mm as compared with the year before harvest, while clearcutting and partial cuts of Eucalyptus did not increase streamflow. During 2008–2019, the combination of emerging drought and forestry treatments (replanting with Eucalyptus after clearcutting of Radiata pine and Eucalyptus) reduced streamflow by 400–500 mm, and regeneration of previously herbicide-treated vegetation combined with growth of Eucalyptus plantations reduced streamflow by 1125 mm (87% of mean annual precipitation 2010–2019). These results from one of the most comprehensive forest catchment studies in the world on private industrial forest land indicate that multiple decades of forest management have reduced deep soil moisture reservoirs. This effect has been exacerbated by drought and conversion from Radiata pine to Eucalyptus, apparently largely eliminating subsurface supply to streamflow. The findings reveal tradeoffs between wood production and water supply, provide lessons for adapting forest management to the projected future drier climate in Chile, and underscore the need for continued experimental work in managed forest plantations.     

Prediction of the calcium carbonate budget in a sedimentary basin: A “source-to-sink” approach applied to Great Salt Lake,Utah, USA

Most source-to-sink studies typically focus on the dynamics of clastic sediments and consider erosion, transport and deposition of sediment particles as the sole contributors. Although often neglected, dissolved solids produced by weathering processes contribute significantly in the sedimentary dynamics of basins, supporting chemical and/or biological precipitation. Calcium ions are usually a major dissolved constituent of water drained through the watershed and may facilitate the precipitation of calcium carbonate when supersaturating conditions are reached. The high mobility of Ca²⁺ ions may cause outflow from an open system and consequently loss. In contrast, in closed basins, all dissolved (i.e. non-volatile) inputs converge at the lowest point of the basin. The endoreic Great Salt Lake basin constitutes an excellent natural laboratory to study the dynamics of calcium on a basin scale, from the erosion and transport through the watershed to the sink, including sedimentation in lake's waterbody. The current investigation focused on the Holocene epoch. Despite successive lake level fluctuations (amplitude around 10 m), the average water level seems to have not been affected by any significant long-term change (i.e. no increasing or decreasing trend, but fairly stable across the Holocene). Weathering of calcium-rich minerals in the watershed mobilizes Ca²⁺ ions that are transported by surface streams and subsurface flow to the Great Salt Lake (GSL). Monitoring data of these flows was corrected for recent anthropogenic activity (river management) and combined with direct precipitation (i.e. rain and snow) and atmospheric dust income into the lake, allowing estimating the amount of calcium delivered to the GSL. These values were then extrapolated through the Holocene period and compared to the estimated amount of calcium stored in GSL water column, porewater and sediments (using hydrochemical, mapping, coring and petrophysical estimates). The similar estimate of calcium delivered (4.88 Gt) and calcium stored (3.94 Gt) is consistent with the premise of the source-to-sink approach: a mass balance between eroded and transported compounds and the sinks. The amount of calcium deposited in the basin can therefore be predicted indirectly from the different inputs, which can be assessed with more confidence. When monitoring is unavailable (e.g. in the fossil record), the geodynamic context, the average lithology of the watershed and the bioclimatic classification of an endoreic basin are alternative properties that may be used to estimate the inputs. We show that this approach is sufficiently accurate to predict the amount of calcium captured in a basin and can be extended to the whole fossil record and inform on the storage of calcium.     

Understanding the Past and Present and Predicting the Future: Farmers’ Use of Multiple Nutrient Best Management Practices in the Upper Midwest

Understanding what drives farmers’ voluntary adoption of nutrient and soil best management practices has important consequences for many environmental outcomes including water quality. We build on research revealing the need for simultaneous use of multiple nitrogen best management practices to achieve water quality improvement goals. Using social, economic and attitudinal variables we predict the use of multiple nitrogen best management practices at three time points: current use (2013), past use (before 2013), and likelihood of use on their largest field in the next three years. Our empirical analysis uses structural equation modeling with latent variables and 2014 farmer survey data from three Midwestern US states. Most farmers in our sample used at least one of the six best management practices. Our results reveal that farmers’ attitudes, use of information sources, and conservation program participation affect the number of nitrogen best management practices concurrently in use at multiple time points.     

Long‐term temporal and spatial patterns in bioeroding sponge distribution at the Abrolhos Bank,Brazil, Southwestern Atlantic

Bioeroding sponges belong to the most dominant bioeroders, significantly contributing to the erosion of coral reefs. Some species are tolerant or even benefit from environmental conditions such as ocean warming, acidification, and eutrophication. In consequence, increases in sponge bioerosion have been observed on some coral reefs over the last decades. The Abrolhos Bank is the largest coral reef system in the South Atlantic. It has been affected by sedimentation, eutrophication, overfishing, and climate change, mainly affecting coastal reefs, and at lesser intensity outer ones as well. This study aimed to describe spatial and temporal patterns in bioeroding sponge distribution in carbonate substrates in the Abrolhos Bank. Photo‐quadrats were used to compare bioeroding sponge abundance between two shallow reefs: a coastal, Pedra de Leste (PL), and an outer reef, Parcel dos Abrolhos (PAB). Each individual was delimitated over the substrate by determining the sponge surface through a line connecting the outermost papillae. The study was conducted over 6 years in 2008–2009 and 2013–2016. Four species of bioeroding sponges were identified: Cliona carteri Ridley, 1881, C. delitrix Pang, 1973, C. cf. schmidtii Ridley, 1881, and Siphonodictyon coralliphagum Rützler, 1971. The distribution and abundance of species varied between the inner and outer reefs and across the years, and displayed certain selectivity for the calcareous substrates recorded. Crustose coralline algae (CCA) were the main substrate excavated by the most abundant bioeroding species, C. carteri, and represented 70% of the substrate types occupied by this sponge (CCA, coral overgrown by CCA and plain coral). The highest abundance of bioeroding sponges observed in photo‐quadrats was 21.3 individuals/m² at the outer reefs (PAB) in 2014. The abundances or areal extents of bioeroding sponges were up to 10 times greater on the outer reefs than on the coastal ones, where sedimentation is higher and more strongly influenced by siliciclastic material. Moreover, a higher herbivorous fish biomass has been reported on outer reefs which could also influence the higher abundance of bioeroding sponges in outer reefs. During the study period of 6 years, an increase in bioeroding sponge abundance was observed at the outer reefs (PAB), with the sea surface temperature increase. As CCA have an important role in reefal cementation and carbonate production in the Abrolhos reefs, a bioerosion impact might be expected, in particular, on the outer reefs.     

Adding the missing third and fourth dimensions to trajectory analysis in carbonate systems

We developed a seismic geomorphology-based procedure to enhance traditional trajectory analysis with the ability to visualize and quantify lateral variability along carbonate prograding-margin types (ramps and rimmed shelves) in 3D and 4D. This quantitative approach analysed the shelf break geometric evolution of the Oligo-Miocene carbonate clinoform system in the Browse Basin and delineated the feedback between antecedent topography and carbonate system response as controlling factor on shelf break rugosity. Our geometrical analysis identified a systematic shift in the large-scale average shelf break strike direction over a transect of 10 km from 62° to 55° in the Oligo-Miocene interval of the Browse Basin, which is likely controlled by far-field allogenic forcing from the Timor Trough collision zone. Plotting of 3D shelf break trajectories represents a convenient way to visualize the lateral variability in shelf break evolution. Shelf break trajectories that indicate contemporaneous along-strike progradation and retrogradation correlate with phases of autogenic slope system re-organization and may be a proxy for morphological stability of the shelf break. Shelf break rugosity and shelf break trajectory rugosity are not inherited parameters and antecedent topography does not dictate long-term differential movement of the shelf margin through successive depositional sequences. The autogenic carbonate system response to antecedent topography smooths high-rugosity areas by filling accommodation and maintains a relatively constant shelf break rugosity of ~150 m. Color-coding of the vertical component in the shelf break trajectory captures the creation and filling of accommodation, and highlights areas of the transect that are likely to yield inconsistent 2D sequence stratigraphic interpretations.     

Molecular distribution, 13C‐isotope,and enantiomeric compositions of carbonaceous chondrite monocarboxylic acids

The water‐soluble organic compounds in carbonaceous chondrite meteorites constitute a record of the synthetic reactions occurring at the birth of the solar system and those taking place during parent body alteration and may have been important for the later origins and development of life on Earth. In this present work, we have developed a novel methodology for the simultaneous analysis of the molecular distribution, compound‐specific δ¹³C, and enantiomeric compositions of aliphatic monocarboxylic acids (MCA) extracted from the hot‐water extracts of 16 carbonaceous chondrites from CM, CR, CO, CV, and CK groups. We observed high concentrations of meteoritic MCAs, with total carbon weight percentages which in some cases approached those of carbonates and insoluble organic matter. Moreover, we found that the concentration of MCAs in CR chondrites is higher than in the other meteorite groups, with acetic acid exhibiting the highest concentration in all samples. The abundance of MCAs decreased with increasing molecular weight and with increasing aqueous and/or thermal alteration experienced by the meteorite sample. The δ¹³C isotopic values of MCAs ranged from ?52 to +27‰, and aside from an inverse relationship between δ¹³C value and carbon straight‐chain length for C₃–C₆ MCAs in Murchison, the ¹³C‐isotopic values did not correlate with the number of carbon atoms per molecule. We also observed racemic compositions of 2‐methylbutanoic acid in CM and CR chondrites. We used this novel analytical protocol and collective data to shed new light on the prebiotic origins of chondritic MCAs.